Organic electronics

Image: Heliatek

Organic solar cells

Organic solar cells combine the flexibility and low weight of plastics with the semiconducting properties of conventional photovoltaics. They do not require toxic or rare elements, and promise the fastest energy payback time of any photovoltaic technology.

We aim to understand the fundamental physics of organic solar cells. Many processes in these materials are incompletely understood, making it difficult to formulate precise design principles for better devices.

For example, it is still unclear exactly how the electrons and holes in organic solar cells overcome their considerable electrostatic attraction, sometimes with nearly 100% efficiency. We have shown that entropy and disorder play a crucial role, often being sufficient to overcome the Coulomb barrier.20

To understanding the fundamental photophysics in organic solar cells and facilitate the rational design of better materials, we often work in close collaboration with experimentalists. Highlights of these collaborations include:

Quantum effects in organic semiconductors

Our work on charge and energy transport has shown that the same kinds of quantum effects that occur in photosynthetic light-harvesting complexes should also be present in organic semiconductor devices. We have shown that, just like in photosynthesis, there is a subtle relationship between quantum effects and the separation of charge carriers at organic heterojunctions.24

Most recently, we have developed a new theory of the quantum dynamics of delocalised carriers and excitons in organic semiconductors, the first fully quantum treatment in three dimensions that includes disorder, delocalisation, and polaron formation.30, 33 We used it to show that a little delocalisation goes a long way: delocalisation over even a few molecules can enhance mobilities by an order of magnitude30 and increase charge-separation efficiencies by a factor of five33.

Our current focus is on extending our techniques to incorporate quantum effects into other fundamental processes in organic electronics—stay tuned or come join us!

Related papers

“Even a little delocalisation produces large kinetic enhancements of charge-separation efficiency in organic photovoltaics”
Daniel Balzer and Ivan Kassal
Preprint: arXiv:2108.05032 (2021).
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In organic photovoltaics, charges can separate efficiently despite their Coulomb attraction being an order of magnitude greater than the available thermal energy. Delocalisation has been suggested to explain this fact, because it could increase the initial separation of charges in the charge-transfer (CT) state, reducing their attraction. However, understanding the mechanism requires a kinetic model of delocalised charge separation, which has proven difficult because it involves tracking the correlated quantum-mechanical motion of the electron and the hole in large simulation boxes required for disordered materials. Here, we report the first three-dimensional simulations of charge-separation dynamics in the presence of disorder, delocalisation, and polaron formation, finding that even slight delocalisation, across less than two molecules, can significantly enhance the charge-separation efficiency, even starting with thermalised CT states. Importantly, delocalisation does not enhance efficiency by reducing the Coulomb attraction; instead, the enhancement is a kinetic effect produced by the increased overlap of electronic states.
“Delocalised kinetic Monte Carlo for simulating delocalisation-enhanced charge and exciton transport in disordered materials”
Daniel Balzer, Thijs J.A.M. Smolders, David Blyth, Samantha N. Hood, and Ivan Kassal
Chem. Sci. 12, 2276 (2021).
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Charge transport is well understood in both highly ordered materials (band conduction) or highly disordered ones (hopping conduction). In moderately disordered materials—including many organic semiconductors—the approximations valid in either extreme break down, making it difficult to accurately model the conduction. In particular, describing wavefunction delocalisation requires a quantum treatment, which is difficult in disordered materials that lack periodicity. Here, we present the first three-dimensional model of partially delocalised charge and exciton transport in materials in the intermediate disorder regime. Our approach is based on polaron-transformed Redfield theory, but overcomes several computational roadblocks by mapping the quantum-mechanical techniques onto kinetic Monte Carlo. Our theory, delocalised kinetic Monte Carlo (dKMC), shows that the fundamental physics of transport in moderately disordered materials is that of charges hopping between partially delocalised electronic states. Our results reveal why standard kinetic Monte Carlo can dramatically underestimate mobilities even in disordered organic semiconductors, where even a little delocalisation can substantially enhance mobilities, as well as showing that three-dimensional calculations capture important delocalisation effects neglected in lower-dimensional approximations.
“Measuring energetic disorder in organic semiconductors using the photogenerated charge-separation efficiency”
Samantha N. Hood, Nasim Zarrabi, Paul Meredith, Ivan Kassal, and Ardalan Armin
J. Phys. Chem. Lett. 10, 3863 (2019).
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Quantifying energetic disorder in organic semiconductors continues to attract attention because of its significant impact on the transport physics of these technologically important materials. Here, we show that the energetic disorder of organic semiconductors can be determined from the relationship between the internal quantum efficiency of charge generation and the frequency of the incident light. Our results for a number of materials suggest that energetic disorder in organic semiconductors could be greater than previously reported, and we advance ideas as to why this may be the case.
“Anomalous exciton quenching in organic semiconductors in the low-yield limit”
Nasim Zarrabi, Aren Yazmaciyan, Paul Meredith, Ivan Kassal, and Ardalan Armin
J. Phys. Chem. Lett. 9, 6144 (2018).
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The dynamics of exciton quenching are critical to the operational performance of organic optoelectronic devices, but their measurement and elucidation remain ongoing challenges. Here, we present a method for quantifying small photoluminescence quenching efficiencies of organic semiconductors under steady-state conditions. Exciton quenching efficiencies of three different organic semiconductors, PC70BM, P3HT, and PCDTBT, are measured at different bulk quencher densities under continuous low-irradiance illumination. By implementing a steady-state bulk-quenching model, we determine exciton diffusion lengths for the studied materials. At low quencher densities we find that a secondary quenching mechanism is in effect, which is responsible for approximately 20% of the total quenched excitons. This quenching mechanism is observed in all three studied materials and exhibits quenching volumes on the order of several thousand cubic nanometers. The exact origin of this quenching process is not clear, but it may be indicative of delocalized excitons being quenched prior to thermalization.
“Increases in the charge-separation barrier in organic solar cells due to delocalization”
Adam Gluchowski, Katherine L. G. Gray, Samantha N. Hood, and Ivan Kassal
J. Phys. Chem. Lett. 9, 1359 (2018).
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Because of the low dielectric constant, charges in organic solar cells must overcome a strong Coulomb attraction in order to separate. It has been widely argued that intermolecular delocalization would assist charge separation by increasing the effective initial electron–hole separation in a charge-transfer state, thus decreasing their barrier to separation. Here we show that this is not the case: including more than a small amount of delocalization in models of organic solar cells leads to an increase in the free-energy barrier to charge separation. Therefore, if delocalization were to improve the charge separation efficiency, it would have to do so through nonequilibrium kinetic effects that are not captured by a thermodynamic treatment of the barrier height.
“Intercalated vs nonintercalated morphologies in donor−acceptor bulk heterojunction solar cells: PBTTT:fullerene charge generation and recombination revisited”
Elisa Collado-Fregoso, Samantha N. Hood, Safa Shoaee, Bob C. Schroeder, Iain McCulloch, Ivan Kassal, Dieter Neher, and James R. Durrant
J. Phys. Chem. Lett. 8, 4061 (2017).
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In this Letter, we study the role of the donor:acceptor interface nanostructure upon charge separation and recombination in organic photovoltaic devices and blend films, using mixtures of PBTTT and two different fullerene derivatives (PC70BM and ICTA) as models for intercalated and nonintercalated morphologies, respectively. Thermodynamic simulations show that while the completely intercalated system exhibits a large free-energy barrier for charge separation, this barrier is significantly lower in the nonintercalated system and almost vanishes when energetic disorder is included in the model. Despite these differences, both femtosecond-resolved transient absorption spectroscopy (TAS) and time-delayed collection field (TDCF) exhibit extensive first-order losses in both systems, suggesting that geminate pairs are the primary product of photoexcitation. In contrast, the system that comprises a combination of fully intercalated polymer:fullerene areas and fullerene-aggregated domains (1:4 PBTTT:PC70BM) is the only one that shows slow, second-order recombination of free charges, resulting in devices with an overall higher short-circuit current and fill factor. This study therefore provides a novel consideration of the role of the interfacial nanostructure and the nature of bound charges and their impact upon charge generation and recombination.
“Electric field and mobility dependent first-order recombination losses in organic solar cells”
Martin Stolterfoht, Safa Shoaee, Ardalan Armin, Hui Jin, Ivan Kassal, Wei Jiang, Paul Burn, and Paul Meredith
Adv. Energy Mater. 7, 1601379 (2017).
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The origin of photocurrent losses in the power-generating regime of organic solar cells (OSCs) remains a controversial topic, although recent literature suggests that the competition between bimolecular recombination and charge extraction determines the bias dependence of the photocurrent. Here the steady-state recombination dynamics is studied in bulk-heterojunction OSCs with different hole mobilities from short-circuit to maximum power point. It is shown that in this regime, in contrast to previous transient extracted charge and absorption spectroscopy studies, first-order recombination outweighs bimolecular recombination of photogenerated charge carriers. This study demonstrates that the first-order losses increase with decreasing slower carrier mobility, and attributes them to either mobilization of charges trapped at the donor:acceptor interface through the Poole–Frenkel effect, and/or recombination of photogenerated and injected charges. The dependence of both first-order and higher-order losses on the slower carrier mobility explains why the field dependence of OSC efficiencies has historically been attributed to charge-extraction losses.
“Entropy and disorder enable charge separation in organic solar cells”
Samantha N. Hood and Ivan Kassal
J. Phys. Chem. Lett. 7, 4495 (2016).
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Although organic heterojunctions can separate charges with near-unity efficiency and on a sub-picosecond timescale, the full details of the charge-separation process remain unclear. In typical models, the Coulomb binding between the electron and the hole can exceed the thermal energy kT by an order of magnitude, making it impossible for the charges to separate before recombining. Here, we consider the entropic contribution to charge separation in the presence of disorder and find that even modest amounts of disorder have a decisive effect, reducing the charge-separation barrier to about kT or eliminating it altogether. Therefore, the charges are usually not thermodynamically bound at all and could separate spontaneously if the kinetics otherwise allowed it. Our conclusion holds despite the worst-case assumption of localised, thermalised carriers, and is only strengthened if mechanisms like delocalisation or 'hot' states are also present.
“Slower carriers limit charge generation in organic semiconductor light-harvesting systems”
Martin Stolterfoht, Ardalan Armin, Safa Shoaee, Ivan Kassal, Paul Burn, and Paul Meredith
Nature Commun. 7, 11944 (2016).
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Blends of electron-donating and -accepting organic semiconductors are widely used as photoactive materials in next-generation solar cells and photodetectors. The yield of free charges in these systems is often determined by the separation of interfacial electron–hole pairs, which is expected to depend on the ability of the faster carrier to escape the Coulomb potential. Here we show, by measuring geminate and non-geminate losses and key transport parameters in a series of bulk-heterojunction solar cells, that the charge-generation yield increases with increasing slower carrier mobility. This is in direct contrast with the well-established Braun model where the dissociation rate is proportional to the mobility sum, and recent models that underscore the importance of fullerene aggregation for coherent electron propagation. The behaviour is attributed to the restriction of opposite charges to different phases, and to an entropic contribution that favours the joint separation of both charge carriers.
“Spectral dependence of the internal quantum efficiency of organic solar cells: Effect of charge generation pathways”
Ardalan Armin, Ivan Kassal, Paul E. Shaw, Mike Hambsch, Martin Stolterfoht, Dani M. Lyons, Jun Li, Zugui Shi, Paul L. Burn, and Paul Meredith
J. Am. Chem. Soc. 136, 11465 (2014).
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The conventional picture of photocurrent generation in organic solar cells involves photoexcitation of the electron donor, followed by electron transfer to the acceptor via an interfacial charge-transfer state (Channel I). It has been shown that the mirror-image process of acceptor photoexcitation leading to hole transfer to the donor is also an efficient means to generate photocurrent (Channel II). The donor and acceptor components may have overlapping or distinct absorption characteristics. Hence, different excitation wavelengths may preferentially activate one channel or the other, or indeed both. As such, the internal quantum efficiency (IQE) of the solar cell may likewise depend on the excitation wavelength. We show that several model high-efficiency organic solar cell blends, notably PCDTBT:PC70BM and PCPDTBT:PC60/70BM, exhibit flat IQEs across the visible spectrum, suggesting that charge generation is occurring either via a dominant single channel or via both channels but with comparable efficiencies. In contrast, blends of the narrow optical gap copolymer DPP-DTT with PC70BM show two distinct spectrally flat regions in their IQEs, consistent with the two channels operating at different efficiencies. The observed energy dependence of the IQE can be successfully modeled as two parallel photodiodes, each with its own energetics and exciton dynamics but both having the same extraction efficiency. Hence, an excitation-energy dependence of the IQE in this case can be explained as the interplay between two photocurrent-generating channels, without recourse to hot excitons or other exotic processes.